Turkish Journal of Chemistry
Synthesis and Properties of Novel Photosensitive Poly(amide-imide)s Containing Chalcone Moiety and Aromatic Diamines in the Main Chain
Six new poly(amide-imide)s were synthesized by the polycondensation reaction of 1,3-bis[4,4'-bis(trimellityimido) phenyl]-2-propenone (6) with 3,3'-diamino diphenyl sulfone (7a), 4,4'-diamino diphenyl sulfone (7b), 4,4'-diamino diphenyl ether (7c), 1,5-diamino naphthalene (7d), 6-phenyl-1,3,5-triazine (7e), and 6-choloro-1,3-diazine (7f) in a medium consisting of N-methyl-2- pyrrolidone, triphenyl phosphite, calcium chloride, and pyridine. The polycondensation reaction produced a series of novel poly(amide-imide)s (8a-f) in high yield and with inherent viscosities between 0.42 and 0.62 dL/g. The resulting polymers were characterized by elemental analysis, viscosity measurement, solubility testing, thermo-gravimetric analysis (TGA & DTG), FT-IR, and UV-VIS spectroscopy.
Chalcone moiety; poly(amid-imide)s; 4, 4'-diamino chalcone; 1, 3-bis[4, 4'-bis(trimellityimido) phenyl]-2-propenone.
FAGHIHI, KHALIL and MOZAFARI, ZOHREH (2008) "Synthesis and Properties of Novel Photosensitive Poly(amide-imide)s Containing Chalcone Moiety and Aromatic Diamines in the Main Chain," Turkish Journal of Chemistry: Vol. 32: No. 6, Article 3. Available at: https://journals.tubitak.gov.tr/chem/vol32/iss6/3