Determination of Iridoid Glycosides from Four Turkish Lamium Species by HPLC-ESI/MS

Authors

FUNDA NURAY YALÇIN
DUYGU KAYA
İHSAN ÇALIŞ
TAYFUN ERSÖZ
ERHAN PALASKA

DOI

-

Abstract

An HPLC-ESI/MS method that enables fast detection and identification of iridoid glycosides is described. Eleven iridoid glycosides known to occur in the genus Lamium-lamalbide, sesamoside, 6-\beta-OH ipolamiide, shanzhiside methyl ester, dehydropenstemoside, barlerin (= 8-O-acetylshanzhiside methyl ester), 6-O-syringyl-8-O- acetylshanzhiside methyl ester, lamerioside, lamiide, eriobioside, and ipolamiide, were identified by means of their retention time and ESI/MS data. This method was successfully applied to the identification of the iridoid composition of the n-butanol extracts of Lamium eriocephalum Bentham subsp. eriocephalum, L. garganicum L. subsp. pulchrum R. Mill, L. garganicum L. subsp. laevigatum Arcangeli, and L. purpureum L. var. purpureum from the Turkish flora.

Keywords

Lamium, Lamiaceae, iridoid glycosides, HPLC, ESI/MS

First Page

457

Last Page

467

Recommended Citation

YALÇIN, FUNDA NURAY; KAYA, DUYGU; ÇALIŞ, İHSAN; ERSÖZ, TAYFUN; and PALASKA, ERHAN (2008) "Determination of Iridoid Glycosides from Four Turkish Lamium Species by HPLC-ESI/MS," Turkish Journal of Chemistry: Vol. 32: No. 4, Article 6. Available at: https://journals.tubitak.gov.tr/chem/vol32/iss4/6