Turkish Journal of Chemistry
Abstract
The monomers namely 6,6'-dicarbonylchloride-2,2'-bipyridine (1) and 6,6'-dihydrazine-2,2'-bipyridine (2) were synthesized and characterized thoroughly. The polyhydrazides (PHZ1 and PHZ2) were obtained by direct polycondensation of 2 with terephtaloylchloride (TPCl}), and novel polyamide (PA1) by direct polycondensation of 1 with hexametyhlenediamine (HMDA}). Polymers with low PDIs were generated in all cases (PD \sim 1.02-1.3). The polymers were characterized by ^1H and ^{13}C NMR, FT-IR, and Gel Permission Chromatography (GPC).
DOI
-
Keywords
Bipyridine, polyamide, hydrazide, polymer, terephtaloylchloride
First Page
355
Last Page
364
Recommended Citation
ŞENGÜL, A, & ARSLAN, H (2008). Synthesis and Characterization of Novel Polyamide and Polyhydrazides Based on the 6,6´-disubstituted-2,2´-bipyridine. Turkish Journal of Chemistry 32 (3): 355-364. https://doi.org/-
