Synthesis and Characterization of Novel Polyamide and Polyhydrazides Based on the 6,6´-disubstituted-2,2´-bipyridine

Authors

ABDURRAHMAN ŞENGÜL
HÜLYA ARSLAN

DOI

-

Abstract

The monomers namely 6,6'-dicarbonylchloride-2,2'-bipyridine (1) and 6,6'-dihydrazine-2,2'-bipyridine (2) were synthesized and characterized thoroughly. The polyhydrazides (PHZ1 and PHZ2) were obtained by direct polycondensation of 2 with terephtaloylchloride (TPCl}), and novel polyamide (PA1) by direct polycondensation of 1 with hexametyhlenediamine (HMDA}). Polymers with low PDIs were generated in all cases (PD \sim 1.02-1.3). The polymers were characterized by ^1H and ^{13}C NMR, FT-IR, and Gel Permission Chromatography (GPC).

Keywords

Bipyridine, polyamide, hydrazide, polymer, terephtaloylchloride

First Page

355

Last Page

364

Recommended Citation

ŞENGÜL, ABDURRAHMAN and ARSLAN, HÜLYA (2008) "Synthesis and Characterization of Novel Polyamide and Polyhydrazides Based on the 6,6´-disubstituted-2,2´-bipyridine," Turkish Journal of Chemistry: Vol. 32: No. 3, Article 8. Available at: https://journals.tubitak.gov.tr/chem/vol32/iss3/8