Turkish Journal of Chemistry
DOI
-
Abstract
4-(Chloroacetyl)diphenyl ether (I) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl_3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (II) derivative was prepared. Then 3 new substituted 4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from 4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for the ligands ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl) pyridine. Mononuclear or binuclear Co(II), Ni(II), Cu(II), and Cd(II) complexes of the ligands were synthesized. The structures of these ligands were identified by FT-IR, ^1H-NMR, and ^{13}C-NMR spectral data and elemental analysis, and the structures of the complexes were identified by FT-IR, ICP-AES, elemental analysis, and magnetic susceptibility measurements.
Keywords
Ketoxime, transition metal complexes, binuclear complexes
First Page
305
Last Page
312
Recommended Citation
COŞKUN, AHMET and YILMAZ, FUNDA (2008) "Synthesis and Characterization of 4-(Alkylaminoisonitrosoacetyl)diphenyl ether and Some of Their Metal Complexes," Turkish Journal of Chemistry: Vol. 32: No. 3, Article 4. Available at: https://journals.tubitak.gov.tr/chem/vol32/iss3/4
