The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N´-Bis(Salicylidene)-o-Phenylenediamine

Authors

JIANNING LIU
BING ZHANG
BOWAN WU
KEJUN ZHANG
SHENLI HU

DOI

-

Abstract

The electrochemical oxidation of anodic Ti, Fe, Cd, Sn, and Pb (=M) into acetonitrile solutions of N,N'-bis(salicylidene)-o-phenylenediamine [SalophH_2] gives the corresponding M(Saloph) complexes in high yield. The mechanism of the electrochemical reactions is discussed. SalophH_2 forms complexes (1:1 molar ratio) with titanium, iron, cadmium, tin, and lead ions. The complexes have been characterized by elemental analyses, molar conductivity measurements, and infrared and electronic spectral data. The SalophH_2 complexes of iron(II) and cadmium(II) have been further identified by ^1H-NMR and mass spectra.

Keywords

Electrochemical Synthesis, N, N'-Bis(Salicylidene)-o-Phenylenediamine, metal complex

First Page

623

Last Page

629

Recommended Citation

LIU, JIANNING; ZHANG, BING; WU, BOWAN; ZHANG, KEJUN; and HU, SHENLI (2007) "The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N´-Bis(Salicylidene)-o-Phenylenediamine," Turkish Journal of Chemistry: Vol. 31: No. 6, Article 8. Available at: https://journals.tubitak.gov.tr/chem/vol31/iss6/8