Turkish Journal of Chemistry
DOI
-
Abstract
Dimethyl bis(4-methylpiperidine dithiocarbamato-S,S')-tin(IV) was synthesized and characterized by elemental analysis, IR and mass spectrometry, multinuclear NMR (^1H- and ^{13}C-NMR), and X-ray single crystal analysis. IR data showed that the ligand acts as a bidentate in the solid state. X-ray data showed the unsymmetrical nature of the ligand towards coordination to tin. It crystallized in the monoclinic P2_1/n space group. Its geometry is distorted octahedral. Antimicrobial activity data shows that the complex exhibits significantly more activity than the free ligand.
Keywords
Dithiocarbamate, NMR, mass, antimicrobial study, X-ray structure
First Page
435
Last Page
442
Recommended Citation
REHMAN, ZIA-UR; SHAHZADI, SAIRA; ALI, SAQIB; and JIN, GUO-XIN (2007) "Preparation, Spectroscopy, Antimicrobial Assay, and X-Ray Structure of Dimethyl bis-(4-methylpiperidine dithiocarbamato-S,S`)-tin(IV)," Turkish Journal of Chemistry: Vol. 31: No. 4, Article 5. Available at: https://journals.tubitak.gov.tr/chem/vol31/iss4/5