Turkish Journal of Chemistry
Abstract
Conducting copolymers were synthesized via the electrochemical oxidation of pyrrole (Py) in the presence of the monomer 1,12-bis(2-thienyl)-2,5,8,11-tetraoxadodecane (I). The presence of monomer I in the electrolytic solution greatly changed the CV behavior of Py during its potensiodynamic polymerization. The electroactivity of poly(I-co-Py) increased with the increasing amount of I in the comonomer mixture. Copolymer films were prepared via constant potential electrolysis in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF_6) dissolved in acetonitrile. The spectroelectrochemical properties of the films were investigated using UV-VIS spectroscopy.
DOI
-
Keywords
Electrochemical polymerization, spectroelectrochemistry, polymer containing pseudo-polyether cages
First Page
629
Last Page
634
Recommended Citation
CİHANER, A, & ÖNAL, A. M (2006). Electrochemical Copolymerization of Thiophene Containing Pseudo-Polyether Cages with Pyrrole. Turkish Journal of Chemistry 30 (5): 629-634. https://doi.org/-
