Turkish Journal of Chemistry
DOI
-
Abstract
This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, ^{13}C NMR, and ^1H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P2_1/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) Å, \beta = 105.892(2) °, V = 1291.00(9) Å^3, and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
Keywords
Schiff Base, Bisformylpyrrole, Macrocycle, Crystal structure
First Page
243
Last Page
251
Recommended Citation
ŞENER, M. KASIM; GARCIA, DAVİD SANCHES; AKKURT, MEHMET; YILDIRIM, SEMA ÖZTÜRK; FUN, HOONG-KUN; and SESSLER, JONATHAN L. (2006) "Synthesis and Crystal Structure of 1,3-Bis(5-formylpyrrol-2-yl)benzene and Its Conversion to a Macrocyclic Derivative," Turkish Journal of Chemistry: Vol. 30: No. 2, Article 13. Available at: https://journals.tubitak.gov.tr/chem/vol30/iss2/13
