Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands (Part 4): Synthesis and Characterization of a New 5-Hydroxysalicyliden-P-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II) and Zn(II)

Authors

ERDAL CANPOLAT
MEHMET KAYA

DOI

-

Abstract

5-Hydroxysalicyliden-p-aminoacetophenoneoxime (LH) was synthesized starting from p-aminoacetophenoneoxime and 5-hydroxysalicylaldehyde. Complexes of this ligand with Co^{+2}, Ni^{+2}, Cu^{+2} and Zn^{+2} salts were prepared. With this ligand, complexes were synthesized using Co^{+2}, Ni^{+2}, Cu^{+2} and Zn^{+2} salt with a metal:ligand ratio of 1:2. Their structures were elucidated on the basis of elemental analyses, IR, ^1H- and ^{13}C-NMR, electronic spectra, magnetic susceptibility measurements, molar conductivity and thermogravimetric analyses.

Keywords

Schiff bases, transition metal complexes, oxim

First Page

409

Last Page

415

Recommended Citation

CANPOLAT, ERDAL and KAYA, MEHMET (2005) "Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands (Part 4): Synthesis and Characterization of a New 5-Hydroxysalicyliden-P-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II) and Zn(II)," Turkish Journal of Chemistry: Vol. 29: No. 4, Article 9. Available at: https://journals.tubitak.gov.tr/chem/vol29/iss4/9