Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag_2(opsp)_2](NO_3)_2

Authors

LI-RONG WEN
MING LI
GUI-LONG ZHAO
XUE-MEI LI
OU-YANG PINGKAI
SHU-SHENG ZHANG

Abstract

The new silver(I) complexe [Ag_2(opsp)_2](NO_3)_2 (1) was synthesized by the self-assembly of AgX (X = NO_3^-) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.

DOI

-

Keywords

Multidentate ligand; Silver(I) complex; Crystal structure; Dinuclear molecule

First Page

193

Last Page

197

Recommended Citation

WEN, L, LI, M, ZHAO, G, LI, X, PINGKAI, O, & ZHANG, S (2005). Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag_2(opsp)_2](NO_3)_2. Turkish Journal of Chemistry 29 (2): 193-197. https://doi.org/-