Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine (GH_2), anti-2-pyridinealdehydeglyoxime hydrazone (PyGH_2) and anti-2-furancarboxaldehydeglyoxime hydrazone (FGH_2). The synthesized anti-glyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH_2 and FGH_2 ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II) ions. The structures of the ligands and complexes were determined by ^1H n.m.r, i.r spectroscopy and elemental analytical techniques.
vic-Dioximes, Glyoximes, Hydrazone compounds, Metal complexes
SARIKAVAKLI, NURSABAH and İREZ, GAZİ (2005) "Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones," Turkish Journal of Chemistry: Vol. 29: No. 1, Article 13. Available at: https://journals.tubitak.gov.tr/chem/vol29/iss1/13