Turkish Journal of Chemistry
Abstract
Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine (GH_2), anti-2-pyridinealdehydeglyoxime hydrazone (PyGH_2) and anti-2-furancarboxaldehydeglyoxime hydrazone (FGH_2). The synthesized anti-glyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH_2 and FGH_2 ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II) ions. The structures of the ligands and complexes were determined by ^1H n.m.r, i.r spectroscopy and elemental analytical techniques.
DOI
-
Keywords
vic-Dioximes, Glyoximes, Hydrazone compounds, Metal complexes
First Page
107
Last Page
116
Recommended Citation
SARIKAVAKLI, N, & İREZ, G (2005). Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones. Turkish Journal of Chemistry 29 (1): 107-116. https://doi.org/-