Turkish Journal of Chemistry
DOI
-
Abstract
The bromination reaction of tricyclo[7.2.1.0^{2,7}]dodeca-2,4,6,10-tetraene derivatives was studied. The bromination of 9 gave only rearranged products 12 and 13, while the bromination of 8 with molecular bromine formed both rearranged 12 and non-rearranged products 15 and 16. The possible role of a substituent in the rearrangements was examined. All compounds were characterized properly, in particular by NMR spectra and chemical transformation.
Keywords
Bromination, Wagner-Meerwein Rearrangement (W.M.R.), Polybromides, Neighboring Group Effect
First Page
715
Last Page
724
Recommended Citation
DAŞTAN, ARİF (2004) "Bromination of Tricyclo[7.2.1.0^{2,7}]dodeca-2,4,6,10-tetraene Derivatives: Electronic and Neighboring Group Effects on Bromination," Turkish Journal of Chemistry: Vol. 28: No. 6, Article 5. Available at: https://journals.tubitak.gov.tr/chem/vol28/iss6/5
