Turkish Journal of Chemistry
DOI
-
Abstract
4,4'-Bis(chloroacetyl)diphenyl thioether (HL) was synthesized from chloroacetyl chloride and diphenyl thioether in the presence of AlCl_3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (H_2L) and glyoxime (H_4L) derivatives were also prepared. Then 3 new substituted 4,4'-thiobis(aminophen- ylglyoxime) (H_4L^{1 - 3}) were synthesized from 4,4'-thiobis(chlorophenylglyoxime) and the corresponding amines. The Ni(II), Cu(II) and Co(II) complexes of these ligands were prepared. The structures of these ligands and their complexes were identifed by FT-IR, ^1H NMR and ICP-AES spectral data, elemental analyses and magnetic measurements.
Keywords
Glyoxime, Transition metal complexes
First Page
173
Last Page
180
Recommended Citation
COŞKUN, AHMET and KARATAŞ, İBRAHİM (2004) "The Synthesis of Substituted 4,4'-Thiobis(Aminophenylglyoxime) and Their Polymeric Metal Complexes with Cu(II), Ni(II) and Co(II) Salts," Turkish Journal of Chemistry: Vol. 28: No. 2, Article 5. Available at: https://journals.tubitak.gov.tr/chem/vol28/iss2/5
