Turkish Journal of Chemistry
DOI
-
Abstract
A series of new electron rich olefins (=\overset{ } CNR(CH_2)_4\overset{ }NR)_2, 3, (a; R = CH_2C_6H_5, b; R = CH_2C_6H_4-OMe-p, c; R = CH_2C_6H_4-NMe_2-p) was generated via the condensation of RNH(CH_2)_4NHR with Me_2NCH (OMe)_2. The C=C bond cleavage reactions of 3 with S_8 and Se provide a simple and straightforward method for the synthesis of 1,3-diazepan-2-chalcogenones 4 and 5, respectively.
Keywords
Thio- and selenoureas, 1, 3-diazepan derivatives, electron rich olefins
First Page
157
Last Page
162
Recommended Citation
GÖK, YETKİN and ÇETİNKAYA, ENGİN (2004) "Chalcogeno Ureas Derived from Bis(1,3-diazepan-2-ylidene)," Turkish Journal of Chemistry: Vol. 28: No. 2, Article 3. Available at: https://journals.tubitak.gov.tr/chem/vol28/iss2/3
