Turkish Journal of Chemistry
DOI
-
Abstract
The reaction of 2-[(2,3-dimethylphenyl)amino]benzoic acid (HL) with tri- and diorganotin(IV) chlorides yielded complexes of the type R_{3}SnL and R_{2}SnL_{2} (R = n-C_{4}H_{9}, C_{6}H_{5}, C_{6}H_{5}CH_{2}, n-C_{8}H_{17}). The compounds R_{2}SnClL were obtained by a redistribution reaction between R_{2}SnL_{2} and R_{2}SnCl_{2}. All the compounds were characterized by CHN analysis, infrared, multinuclear NMR, mass and Mössbauer spectroscopy. The possible mode of carboxylate group bonding in solid as well as in solution is proposed on the basis of infrared, Mössbauer and NMR (^{1}H, ^{13}C, ^{119}Sn) spectroscopy.
First Page
75
Last Page
86
Recommended Citation
MASOOD, HAJRA; ALI, SAQIB; MAZHAR, MOHUMMAD; SHAHZADI, SAIRA; and SHAHID, KHADIJA (2004) "^{1}H, ^{13}C, ^{119}Sn NMR, Mass, Mössbauer and Biological Studies of Tri-,Di- and Chlorodiorganotin(IV) Carboxylates," Turkish Journal of Chemistry: Vol. 28: No. 1, Article 9. Available at: https://journals.tubitak.gov.tr/chem/vol28/iss1/9
