Turkish Journal of Chemistry
DOI
-
Abstract
In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P2_{1}/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, \beta = 93.90(1)°, and D_{calc} = 1.616 g cm^{-1} for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.
Keywords
Complex, X-ray structure, single crystal, N, N-dimethyl-N'- benzoylthiourea
First Page
281
Last Page
286
Recommended Citation
AVŞAR, GÖKTÜRK; ARSLAN, HAKAN; HAUPT, HANS-JURGEN; and KÜLCÜ, NEVZAT (2003) "Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)," Turkish Journal of Chemistry: Vol. 27: No. 3, Article 1. Available at: https://journals.tubitak.gov.tr/chem/vol27/iss3/1
