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Turkish Journal of Chemistry

DOI

-

Abstract

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

Keywords

Bromination, benzonorbornadiene, high temperature bromination, sodium perborate.

First Page

939

Last Page

946

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