Synthesis, Characterization and Thermal Analysis of Organotin(IV) Derivatives of 4-(N-Maleoyl)Butanoate

Authors

KHADIJA SHAHID
SAQIB ALI
MOAZZAM H. BHATTI
MUHAMMAD MAZHAR
SOHAIL MAHMOOD
SADIQUR REHMAN

DOI

-

Abstract

Organotin(IV) derivatives of the type R_{4 - n}SnL_{n} where R = Me, n-Bu, Ph, L = 4 - (N-maleoyl)butanoate and n = 1 or 2 were synthesized by refluxing R_{3}SnCl and R_{2}SnCl_{2} with (4-(N-maleoyl)butanoate in the presence of triethylamine using dry toluene as solvent. These compounds were characterized by IR, multinuclear NMR and mass spectrometry. We also studied their thermal behavior and calculated the degradation pattern, energy of activation (E_{a}) and order of reaction (n).

First Page

589

Last Page

598

Recommended Citation

SHAHID, KHADIJA; ALI, SAQIB; BHATTI, MOAZZAM H.; MAZHAR, MUHAMMAD; MAHMOOD, SOHAIL; and REHMAN, SADIQUR (2002) "Synthesis, Characterization and Thermal Analysis of Organotin(IV) Derivatives of 4-(N-Maleoyl)Butanoate," Turkish Journal of Chemistry: Vol. 26: No. 4, Article 17. Available at: https://journals.tubitak.gov.tr/chem/vol26/iss4/17