Turkish Journal of Chemistry
DOI
-
Abstract
Bismuth(III) (0-25 \mu g/ml) is determined spectrophotometricaly at 513 nm after extraction into dichloromethane of the ion associate di-(hydrogenatedtallowalkyl)dimethylammonium tetraiodobismuthate. The reagent stream is distilled water, merged with 1.0 M sulfuric acid, 5% potassium iodide and 5% (w/v) ascorbic acid solution. The reagent stream is 0.2% (w/v) di-(hydrogenatedtallowalkyl)dimethylammonium chloride solution. The injection rate is 15 h^{-1}. The calibration graph is linear up to 25 \mu g/ml. The detection limit is 0.35 \mu g/ml Bi. The system is applied on water samples and copper-based alloys.
Keywords
Extraction, Flow-Injection, Bismuth, Di-(hydrogenatedtallowalkyl)dimethylammonium chloride.
First Page
345
Last Page
350
Recommended Citation
BARAKAT, S. A. (2002) "Flow Injection Extraction - Spectrophotometric Determination of Bismuth with Di-(hydrogenated tallow alkyl) dimethylammonium Chloride," Turkish Journal of Chemistry: Vol. 26: No. 3, Article 6. Available at: https://journals.tubitak.gov.tr/chem/vol26/iss3/6