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Turkish Journal of Chemistry

Authors

S. A. BARAKAT

DOI

-

Abstract

Bismuth(III) (0-25 \mu g/ml) is determined spectrophotometricaly at 513 nm after extraction into dichloromethane of the ion associate di-(hydrogenatedtallowalkyl)dimethylammonium tetraiodobismuthate. The reagent stream is distilled water, merged with 1.0 M sulfuric acid, 5% potassium iodide and 5% (w/v) ascorbic acid solution. The reagent stream is 0.2% (w/v) di-(hydrogenatedtallowalkyl)dimethylammonium chloride solution. The injection rate is 15 h^{-1}. The calibration graph is linear up to 25 \mu g/ml. The detection limit is 0.35 \mu g/ml Bi. The system is applied on water samples and copper-based alloys.

Keywords

Extraction, Flow-Injection, Bismuth, Di-(hydrogenatedtallowalkyl)dimethylammonium chloride.

First Page

345

Last Page

350

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