Turkish Journal of Chemistry
Article Title
DOI
-
Abstract
The structures and electronic properties of N-hydroxyamide ethoxycarbonylhydrazones were investigated by a quantum-chemical method AMl. The total energies, heats of formation, dipol moments, ionization potentials, proton affinities and energies of frontier molecular orbitals (E_{HOMO} and E_{LUMO}) were calculated and discussed. The stabilities of the tautomeric forms and of E and Z isomers for these compounds were determined. The complex forming ability of these compounds with metal cations was also studied. The geometry and electronic properties of the complexes formed by N-hydroxyacetamide ethoxycarbonylhydrazone with Ni^{2+} and Cu^{2+} were investigated using ZINDO/1 semiempirical method. Moreover, these complexes were synthesized and identified.
First Page
1
Last Page
8
Recommended Citation
İKİZLER, A. AYKUT; DEMİRBAŞ, AHMET; and ABBASOĞLU, RZA (2000) "A Study on N-Hydroxyamide Ethoxycarbonylhydrazones," Turkish Journal of Chemistry: Vol. 24: No. 1, Article 1. Available at: https://journals.tubitak.gov.tr/chem/vol24/iss1/1
