Reaction Mechanism and Kinetics of Aqueous Solutions of Primary and Secondary Alkanolamines and Carbon Dioxide

Authors

OLGAC BAVBEK
ERDOĞAN ALPER

DOI

-

Abstract

The mechanism and kinetics of the reaction between aqueous solutions of CO_2 and the alkanolamines 1-amino-2-propanol, 3-amino-1-propanol,2-methyl aminoethanol and 2-ethyl aminoethanol were investigated using a stopped flow technique. It was found that the reaction orders according to power law kinetics were between 1.1 and 2.0, depending on the alkanolamine and the concentration ranges investigated. This fractional order was therefore considered to be further evidence that carbamate formation takes place according to a zwitterion mechanism rather than a one-step reaction. The kinetic rate parameters for these alkanolamines were evaluated from experimental data at 303 K according to this mechanism.

First Page

293

Last Page

300

Recommended Citation

BAVBEK, OLGAC and ALPER, ERDOĞAN (1999) "Reaction Mechanism and Kinetics of Aqueous Solutions of Primary and Secondary Alkanolamines and Carbon Dioxide," Turkish Journal of Chemistry: Vol. 23: No. 3, Article 8. Available at: https://journals.tubitak.gov.tr/chem/vol23/iss3/8