Turkish Journal of Chemistry
DOI
-
Abstract
The dissociation constant of the catechol derivatives 4-nitrocatechol (NCAT), 2,3-dihydroxybenzoic acid (2,3-DHBA), 3,4-dihydroxybenzoic acid (3,4-DBHA), 3,4-dihydroxyhenylacetic acid (3,4-DPHA) and 3,4-dihydroxycinnamic acid (3,4-DHCA) were identified in 0.1M NaClO_4 ionic medium, at t=25^{\circ}C, by potentiometry. In addition, the first and second dissociation constants of the salicylic acid derivatives 5-nitrosalicylic acid (5-NSA), 4-hydroxysalicylic acid (4-HSA) 5-nitrosalicylic acid (5-HSA) were also determined by potentiometry. Furthermore, the second acid dissociation constants of these ligands were evaluated in I=0.1M NaClO_4 ionic medium, at a temperature of 25^{\circ}C by computer analysis of spectroscopic data.
Keywords
Acid dissociation constants, catechol derivatives, salicylic acid derivatives.
First Page
428
Last Page
436
Recommended Citation
AYDIN, Rahmiye; ÖZER, Ulviye; and TÜRKEL, Naciye (1997) "Potentiometric and Spectroscopic Determinaton of Acid Dissociation Constants of Some Phenols and Salicylic Acids," Turkish Journal of Chemistry: Vol. 21: No. 4, Article 27. Available at: https://journals.tubitak.gov.tr/chem/vol21/iss4/27
