Some Oxidation Reactions of Isomeric Pyridinecarboxylic Acid Hydrazides

Authors

Rashid IQBAL
Samia EBRAHIM
Muhammad ZIAULHAQ

DOI

-

Abstract

The oxidation reactions of the three isomeric pyridinecarboxylic acid hydrazides were studied using sodium metaperidoate, silver(I) oxide and potassium ferricyanide separately. Potassium ferricyanide emerged as an excellent reagent for preparation of 2-pyridinecarboxaldehyde and 3-pyridinecarboxaldehyde from the respective isomeric pyridinecarboxylic acid hydrazides. Oxidation with silver(I) oxide in each case yielded the corresponding 1,2-dipyridoylhydrazine, while sodium metaperiodate furnished different products with each isomeric pyridinecarboxylic acid hyrazide.

First Page

200

Last Page

208

Recommended Citation

IQBAL, Rashid; EBRAHIM, Samia; and ZIAULHAQ, Muhammad (1997) "Some Oxidation Reactions of Isomeric Pyridinecarboxylic Acid Hydrazides," Turkish Journal of Chemistry: Vol. 21: No. 3, Article 8. Available at: https://journals.tubitak.gov.tr/chem/vol21/iss3/8