Turkish Journal of Chemistry
Article Title
Extractive Spectrophotometry of Palladium(II) With 3,4,5- Trimethoxybenzaldehyde Thiosemicarbazone
DOI
-
Abstract
The extractive spectrophotometric determination of palladium(II) using 3,4, 5-trimethoxybenzaldehyde thiosemicarbazone (TBTSC) is discussed in this study. It forms an intense yellow-coloured chloroform-soluble complex with paladium(II) in an acidic medium. The molar absorptivity at 370nm is 8.35x 10^{4} 1. mol^{-1} cm^{-1}. The complex system conformed to Beer's Law up to a concentration limit of 12 ppm. The Sandell's sensitivity was 8. 57 ng. cm^{-2}. The interference of various ions was studied, and palladium(II) in its alloy compositions was analysed.
First Page
222
Last Page
227
Recommended Citation
KHADER, A. M. A. and PRASAD, K. S. (1996) "Extractive Spectrophotometry of Palladium(II) With 3,4,5- Trimethoxybenzaldehyde Thiosemicarbazone," Turkish Journal of Chemistry: Vol. 20: No. 3, Article 6. Available at: https://journals.tubitak.gov.tr/chem/vol20/iss3/6
