Turkish Journal of Physics
Abstract
Plasmonic nanostructures offer an effective route for enhancing light-matter interaction in atomically thin semiconductors, whose optical response is intrinsically limited by their subnanometer active thickness. Here, we numerically investigate excitonic enhancement in monolayer (ML) Molybdenum Disulfide (MoS2) coupled to size-tuned gold (Au) nanocube arrays separated by thin aluminum oxide (Al2O3) and hexagonal boron nitride (h-BN) spacer layers. By varying the nanocube side length, the localized surface plasmon resonance is tuned across the visible spectral range to modulate the A- and B-excitonic transitions of monolayer MoS2.We show that the nanocube-size-dependent spectral redshift can be further controlled through the spacer material and thickness, enabling systematic tuning of the near-field distribution, carrier generation rate, antenna quantum yield, and radiative decay enhancement. Localized plasmonic confinement yields excitation-rate enhancements of up to 4.35 at B-excitonic transition (605 nm) and 3.66 at A-excitonic transition (650 nm), while the radiative decay-rate enhancement exceeds 80, leading to 350-fold local photoluminescence enhancement. Although both A- and B-excitonic channels are enhanced simultaneously, their relative contributions depend on nanocube size, spacer material, and spacer thickness, indicating wavelength-dependent excitonic modulation rather than strict exciton-selective switching. These findings establish Au nanocube arrays as a simple, scalable, and tunable plasmonic platform for enhancing excitonic carrier generation and emission in ML MoS2.
DOI
10.55730/1300-0101.2943
Keywords
Monolayer MoS2, exciton-plasmon coupling, purcell enhancement, charge generation rate
First Page
324
Last Page
340
Publisher
The Scientific and Technological Research Council of Türkiye (TÜBİTAK)
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Recommended Citation
YILDIZ, A. E, & POLAT, E. O (2026). Spacer-mediated gold nanocube arrays for edge-localized excitonic enhancement in monolayer MoS2. Turkish Journal of Physics 50 (5): 324-340. https://doi.org/10.55730/1300-0101.2943
