Turkish Journal of Chemistry
Article Title
DOI
10.3906/kim-0810-50
Abstract
Investigation on the total synthesis of batrachotoxin 1 revealed that the cyclic ketals could be cleaved to ketone with IBX in DMSO at 70-81 °C under very mild conditions. A variety of functional groups showed no interference under these conditions except vinyl bromides, which, in fact, inhibits the single electron transfer to IBX.
First Page
209
Last Page
214
Recommended Citation
RAZA, ABDUL RAUF
(2009)
"A Mild Method for the Cleavage of Ketals Using IBX,"
Turkish Journal of Chemistry: Vol. 33:
No.
2, Article 3.
https://doi.org/10.3906/kim-0810-50
Available at:
https://journals.tubitak.gov.tr/chem/vol33/iss2/3
