Authors: YAVUZ TAŞKESENLIGIL, FERHAN TÜMER, CAVİT KAZAZ, METİN BALCI
Abstract: In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.
Keywords: Cyclic allene, Cyclic alkynes, Deuterium Labeling
Full Text: PDF